α-Hydroxyiminophosphonate, -phosphinate and -phosphonium Derivatives
- Autoría:
- Javier Vicario, Concepcion Alonso, Jesus M. de los Santos, Francisco Palacios
- Año:
- 2010
- Revista:
- Current Organic Synthesis
- Volumen:
- 7
- Página de inicio - Página de fin:
- 628 - 649
- Descripción:
-
The structural and synthetic aspects related to α-oxyiminophosphorus derivatives are reviewed. This includes their preparation through reactions involving C-N double bond or P-C single bond formation as well as the O-functionalization or transformations at the phosphorus atom of other phosphorus substituted oximes. Moreover the synthetic features of α-oxyiminophosphorus derivatives include the reduction of the oximo group with selective preparation of biologically active α-amino-phosphonate and -phosphinate derivatives, as well as the oxidative transformations on the oxime group, rearrangement versus fragmentation reactions, radical reactions and formation of metal complexes