"Late-Stage C–H Acylation of Tyrosine-Containing Oligopeptides with Alcohols"

Urruzuno, I.; Andrade-Sampedro, P.; Correa, A.*

Org. Lett. 2021, 23, 7279-7284

"Metal-Catalyzed C(sp²)–H Functionalization Processes of Phenylalanine- and Tyrosine-Containing Peptides"

Correa, A.*

Eur. J. Inorg. Chem. 2021, 2928–2941

Special Collection for the Winners of the Spanish GEQO-RSEQ Awards

"Pd-Catalyzed C–H Alkoxycarbonylation of Phenethyl- and Benzylamines with Chloroformates as CO Surrogates"

Andrade-Sampedro, P.; Matxain, J. M.; Correa, A.*

Chem. Eur. J. 2021, 27, 5782 – 5789

"Site-Selective Aqueous C–H Acylation of Tyrosine-Containing Oligopeptides with Aldehydes"

San Segundo, M.; Correa, A.*

Chem. Sci. 2020, 11, 11531–11538

Patente: ES-2849373_A1; WO2021165233

Highlighted in Synfacts 2021, 17, 0105

"On the Mechanism of Cross-Dehydrogenative Couplings between N-Aryl Glycinates and Indoles: A Computational Study"

Andrade-Sampedro, P.; Correa, A.;* Matxain, J. M.*

J. Org. Chem. 2020, 85, 13133-13140

"Site‐Selective Trifluoromethylation Reactions of Oligopeptides"

Guerrero, I.; Correa, A.*

Asian J. Org. Chem. 2020, 9, 898-909 (Invited Review)

"Cu-Catalyzed Site-Selective C(sp²)–H Radical Trifluoromethylation of Tryptophan-Containing Peptides"

Guerrero, I.; Correa, A.*

Org. Lett. 2020, 22, 1754-1759

(Highlighted in Synfacts 2020, 16, 609)

"Pd-Catalyzed Site-Selective C(sp²)-H Radical Acylation of Phenylalanine-Containing Peptides with Aldehydes"

San Segundo, M.; Correa, A.*

Chem. Sci. 2019, 10, 8872 - 8879

(Highlighted in Synfacts 2019, 15, 1327)

"Site-Selective Cu-Catalyzed Alkylation of α-Amino Acids and Peptides toward the Assembly of Quaternary Centers"

San Segundo, M.; Correa, A.*

ChemSusChem 2018, 11, 3893-3898.

"Metal-catalyzed C-H functionalization processes upon "click"-triazole assistance"

Guerrero, I.; Correa, A.*

Eur. J. Org. Chem. 2018, 6034-6049 (Special Issue on CHAOS)

Top Downloaded Paper 2018-2019

"Cross-Dehydrogenative Coupling Reactions for the Functionalization of α-Amino Acid Derivatives and Peptides"

San Segundo, M.; Correa, A.*

Synthesis 2018, 50, 2853-2866 (Invited Review)

 "Iron-Catalyzed C(sp³)-H Functionalization of N,N-Dimethylanilines with Isocyanides"

Guerrero, I.; San Segundo, M.; Correa, A.*

Chem. Commun. 2018, 54, 1627-1630.

"Co-Catalyzed C(sp³)-H Oxidative Coupling of Glycine and Peptide Derivatives"

San Segundo, M.; Guerrero, I.; Correa, A.*

Org. Lett. 2017, 19, 5288-5291.

(Among the most read articles in September 2017)

"Selective C(sp²)−H Halogenation of "click" 4-Aryl-1,2,3-triazoles"

Goitia, A.; Gómez-Bengoa, E.; Correa, A.*

Org. Lett. 2017, 19, 962-965.

(Among the most read articles in February 2017)

(Highlighted in Synfacts 2017, 13, 469)

"Ni- and Fe-Based Cross-Coupling Reactions"

Ed. Correa, A.

Topics in Current Chemistry, 2016,  374, 1-338.

"Triazole-Directed Pd-Catalyzed C(sp²)–H Oxygenation of Arenes and Alkenes"

Irastorza, A.; Aizpurua, J. M.; Correa, A.*

Org. Lett. 2016, 18, 1080-1083.

"Iron-catalyzed α–arylation of ethers with heterocycles"

Correa, A.*; Fiser, B.; Gómez-Bengoa, E.

Chem. Commun. 2015, 51, 13365-13368.

A ) Postdoctoral Researcher at Martin  Group (ICIQ)

1.-"Metal-catalyzed reductive coupling reactions of organic halides with carbonyl-type compounds" Moragas, T.; Correa, A.; Martin, R. Chem. Eur. J. 2014, 20, 8242-8258.

2.-"Ni-catalyzed direct reductive amidation via C−O bond cleavage" Correa, A.; Martin, R. J. Am. Chem. Soc. 2014, 136, 7253-7256.

3.-"Ni-catalyzed carboxylation of C(sp²)− and C(sp³)−O bonds with CO₂" Correa, A.; León, T.; Martin, R.  J. Am. Chem. Soc. 2014, 136, 1062-1069.

4.-"Formal  alkynylation of ketones via Pd-catalyzed C–C bond cleavage"  Ziadi, A.; Correa, A.; Martin, R. Chem. Commun. 2013, 4286-4288.

5.-"Ni-catalyzed decarbonylative C–H coupling reactions: a new strategy for preparing bis(heteroaryl) backbones" Correa, A.; Cornella, J.; Martin, R. Angew. Chem. Int. Ed. 2013, 52, 1878-1880.

 6.-"Ni-catalyzed direct carboxylation of benzyl halides with CO₂"  León, T.; Correa, A.; Martin, R.  J. Am. Chem. Soc. 2013, 135, 1221-1224.

 7.-"1,10-Phenathroline" Correa, A.; Martin, R. e-EROS Encyclopedia of reagents for organic synthesis 2012, 1-3.

8.-"Synergistic palladium-catalyzed C(sp³)–H activation/C(sp³)–O bond formation: a direct, step economical route to benzolactones" Novak, P.; Correa, A.; Gallardo-Donaire, J.; Martin, R. Angew. Chem. Int. Ed. 2011, 50, 12236-12239.

9.-"Pd-catalyzed intramolecular acylation of aryl bromides via C–H functionalization. A highly efficient synthesis of benzocyclobutenones" Álvarez-Bercedo, P.; Flores-Gaspar, A.; Correa, A.; Martin, R. J. Am. Chem. Soc. 2010, 132, 466-467.

 10.-"Metal-catalyzed carboxylation of organometallic reagents with carbon dioxide" Correa, A.; Martin, R.  Angew. Chem. Int. Ed. 2009, 48, 6201-6204.

11.- "Palladium-catalyzed direct carboxylation of aryl bromides with carbon dioxide" Correa, A.; Martin, R.  J. Am. Chem. Soc. 2009, 131, 15974–15975.

12.-"Process for the carboxylation of aryl halides with palladium catalysts" Correa, A.; Martin, R. EP2311788 (A1).

B) Postdoctoral Researcher at Bolm Group (RWTH Aachen University)

 1.-"Metal-catalyzed C(sp²)–N bond formation"
Correa, A.; Bolm, C. Topics in Organometallic Chemistry (Ed. M. Taillefer, D. Ma)
Eds.; Springer Verlag, 2013, 46, 55-85.

2.-"Catalyzed Ullmann type cross-couplings with submol% of copper" Larsson, P.-F.; Correa, A.; Carril, M.; Norrby, P.-O.; Bolm, C. Angew. Chem. Int. Ed. 2009, 48, 5691-5693.

3.-"Synthesis of diarylamines catalyzed by iron salts"
Correa, A.; Carril, M.; Bolm, C. Chem. Eur. J. 2008, 14, 10919-10922.

4.-"Iron-catalysed carbon-heteroatom and heteroatom-heteroatom bond forming processes" Correa, A.; Mancheño, O.; Bolm, C. Chem. Soc. Rev. 2008, 37, 1108-1117.

5.-"Iron-catalyzed Sonogashira couplings" Carril, M.; Correa, A.; Bolm, C. Angew. Chem. Int. Ed. 2008, 47, 4862-4865.

6.-"Iron-catalyzed S-arylation of thiols with aryl iodides" Correa, A.; Carril, M.; Bolm, C. Angew. Chem. Int. Ed. 2008, 47, 2880-2883

7.-"Iron-catalyzed C–O cross-coupling of phenols with aryl iodides" Bistri, O.; Correa, A.; Bolm, C. Angew. Chem. Int. Ed. 2008, 47, 586-588.

8.-"Iron-catalyzed C–N cross-coupling of sulfoximines with aryl iodides" Correa, A.; Bolm, C. Adv. Synth. Catal. 2008, 350, 391-394.

9.-"Iron-Catalyzed N-arylation of amides" Correa, A.; Elmore, S.; Bolm, C. Chem. Eur. J. 2008, 14, 3527-3529.

10.- "Ligand-free copper-catalyzed N-arylation of nitrogen nucleophiles" Correa, A.; Bolm, C. Adv. Synth. Catal. 2007, 349, 2673-2676.

11.-"Iron-catalyzed N-arylation of nitrogen nucleophiles" Correa, A.; Bolm, C. Angew. Chem. Int. Ed. 2007, 46, 8862-8865.

C) PhD thesis (Domínguez Group)

1.-"On the PIFA-mediated olefin amidohydroxylation reaction" Tellitu, I.; Urrejola, A.; Serna, S.; Moreno, I.; Herrero, M. T.; Domínguez, E.; SanMartin, R.; Correa, A. Eur. J. Org. Chem. 2007, 3, 437-444.

2.-"An advantageous synthesis of new indazolone and pyrazolone derivatives" Correa, A.; Tellitu, I.; Domínguez, E.; SanMartin, R. Tetrahedron 2006, 62, 11100-11105.

3.- "A metal-free approach to the synthesis of indoline derivatives by a PIFA-mediated amidohydroxilation reaction" Correa, A.; Tellitu, I.; Domínguez, E.; SanMartin, R. J. Org. Chem. 2006, 71, 8316-8319.

4.- "A novel alternative for the N–S bond formation and its application to the synthesis of  benzisothiazol-3-ones" Correa, A.; Tellitu, I.; Domínguez, E.; SanMartin, R. Org. Lett. 2006, 8, 4811-4813

5.- "A novel alternative for the N–N bond formation through a PIFA-mediated oxidative cyclization and its application to the synthesis of indazol-3-ones" Correa, A.; Tellitu, I.; Domínguez, E.; SanMartin, R. J. Org. Chem. 2006, 71, 3501-3505.

6.- "On the mechanism of the copper-catalyzed enantioselective 1,4-addition of Grignard reagents to unsaturated carbonyl compounds" Harutyunyan, S. R.; López, F.; Browne, W. R.; Correa, A.; Peña, D.; Badorrey, R.; Meetsma, A.; Minnaard, A. J.; Feringa, B. L. J. Am. Chem. Soc. 2006, 128, 9103-9118.

7.- "An efficient, PIFA mediated approach to benzo-, naphtho-, and heterocycle-fused pyrrolo[2,1-c][1,4]diazepines. An advantageous access to the antitumor antibiotic DC-81" Correa, A.; Tellitu, I.; Domínguez, E.; Moreno, I.; SanMartin, R.  J. Org. Chem. 2005, 70, 2256-2264.

8.- "An alternative approach towards novel heterocycle-fused 1,4-diazepin-2-ones by an aromatic amidation protocol" Correa, A.; Herrero, M. T.; Tellitu, I.; Domínguez, E.; Moreno, I.; SanMartin, R. Tetrahedron 2003, 59, 7103-7110.